{"id":2023,"date":"2019-08-25T07:01:18","date_gmt":"2019-08-25T07:01:18","guid":{"rendered":"http:\/\/kalakavan.com\/thickeners-2\/"},"modified":"2019-12-19T19:48:55","modified_gmt":"2019-12-19T20:48:55","slug":"thickeners-in-adhesives","status":"publish","type":"page","link":"https:\/\/kalakavan.com\/en\/thickeners-in-adhesives\/","title":{"rendered":"Thickeners in Adhesives"},"content":{"rendered":"<p><div class=\"fusion-fullwidth fullwidth-box nonhundred-percent-fullwidth non-hundred-percent-height-scrolling fusion-equal-height-columns\"  style='background-color: rgba(255,255,255,0);background-position: left top;background-repeat: no-repeat;padding-right:0px;padding-left:0px;border-top-width:0px;border-bottom-width:0px;border-color:#e8eaf0;border-top-style:solid;border-bottom-style:solid;'><div class=\"fusion-builder-row fusion-row \"><div  class=\"fusion-layout-column fusion_builder_column fusion_builder_column_1_2 fusion-builder-column-1 fusion-one-half fusion-column-first 1_2\"  style='margin-top:30px;margin-bottom:0px;width:50%;width:calc(50% - ( ( 9% ) * 0.5 ) );margin-right: 9%;'>\n\t\t\t\t\t<div class=\"fusion-column-wrapper\" style=\"padding: 0px 0px 0px 0px;background-position:left top;background-repeat:no-repeat;-webkit-background-size:cover;-moz-background-size:cover;-o-background-size:cover;background-size:cover;\"   data-bg-url=\"\">\n\t\t\t\t\t\t<div class=\"fusion-column-content-centered\"><div class=\"fusion-column-content\"><div class=\"fusion-title title fusion-title-1 fusion-sep-none fusion-title-size-two\" style=\"margin-top:10px;margin-bottom:20px;\"><h2 class=\"title-heading-left\" style=\"margin:0;\"><h2 style=\"padding-bottom: 5px;\">Thickeners<\/h2><\/h2><\/div><div class=\"fusion-sep-clear\"><\/div><div class=\"fusion-separator fusion-full-width-sep sep-none\" style=\"margin-left: auto;margin-right: auto;margin-top:15px;\"><\/div><div class=\"fusion-text\"><p style=\"text-align: justify;\">Rheology modifying is one of the crucial issue in fluids. Thickeners play an important role in this part. Wide range of thickeners can be used for this purpose, but the most common ones including cellulosic, ASE and HASE, fumed silica, HEUR (polyurethane thickeners). Different industries like Paints and Coatings, Ink, etc. can take advantage of these products.<\/p>\n<p style=\"text-align: justify;\">Thickeners are known as rheology modifiers which are able to increase viscosity. furthermore, they can provide with different features like water retention, increasing open \u2013time, scrub resistance, anti-sagging, etc.<\/p>\n<p style=\"text-align: justify;\">The most common thickeners in paints and coatings, resins and water-based adhesives:<\/p>\n<\/div><ul class=\"fusion-checklist fusion-checklist-1\" style=\"font-size:14px;line-height:23.8px;\"><li class=\"fusion-li-item\"><span style=\"height:23.8px;width:23.8px;margin-right:9.8px;\" class=\"icon-wrapper circle-no\"><i class=\"fusion-li-icon fa-check-circle fas\" style=\"color:#a8cf45;\"><\/i><\/span><div class=\"fusion-li-item-content\" style=\"margin-left:33.6px;\">Cellulose thickeners<\/div><\/li><li class=\"fusion-li-item\"><span style=\"height:23.8px;width:23.8px;margin-right:9.8px;\" class=\"icon-wrapper circle-no\"><i class=\"fusion-li-icon fa-check-circle fas\" style=\"color:#a8cf45;\"><\/i><\/span><div class=\"fusion-li-item-content\" style=\"margin-left:33.6px;\">Acrylate thickeners (ASE and HASE)<\/div><\/li><li class=\"fusion-li-item\"><span style=\"height:23.8px;width:23.8px;margin-right:9.8px;\" class=\"icon-wrapper circle-no\"><i class=\"fusion-li-icon fa-check-circle fas\" style=\"color:#a8cf45;\"><\/i><\/span><div class=\"fusion-li-item-content\" style=\"margin-left:33.6px;\">Polyurethane thickeners (HEUR)<\/div><\/li><\/ul><\/div><\/div><div class=\"fusion-clearfix\"><\/div>\n\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div><div  class=\"fusion-layout-column fusion_builder_column fusion_builder_column_1_2 fusion-builder-column-2 fusion-one-half fusion-column-last 1_2\"  style='margin-top:30px;margin-bottom:0px;width:50%;width:calc(50% - ( ( 9% ) * 0.5 ) );'>\n\t\t\t\t\t<div class=\"fusion-column-wrapper\" style=\"padding: 0px 0px 0px 0px;background-position:left top;background-repeat:no-repeat;-webkit-background-size:cover;-moz-background-size:cover;-o-background-size:cover;background-size:cover;\"   data-bg-url=\"\">\n\t\t\t\t\t\t<div class=\"fusion-column-content-centered\"><div class=\"fusion-column-content\"><div class=\"imageframe-align-center\"><span class=\"fusion-imageframe imageframe-none imageframe-1 hover-type-none\"><img decoding=\"async\" src=\"http:\/\/kalakavan.com\/wp-content\/uploads\/2019\/03\/11.png\" width=\"\" height=\"\" alt=\"Thickeners\" title=\"Thickeners\" class=\"img-responsive wp-image-1574\" srcset=\"https:\/\/kalakavan.com\/wp-content\/uploads\/2019\/03\/11-200x200.png 200w, https:\/\/kalakavan.com\/wp-content\/uploads\/2019\/03\/11-400x400.png 400w, https:\/\/kalakavan.com\/wp-content\/uploads\/2019\/03\/11-600x600.png 600w, https:\/\/kalakavan.com\/wp-content\/uploads\/2019\/03\/11.png 800w\" sizes=\"(max-width: 800px) 100vw, 600px\" \/><\/span><\/div><\/div><\/div><div class=\"fusion-clearfix\"><\/div>\n\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><div class=\"fusion-fullwidth fullwidth-box nonhundred-percent-fullwidth non-hundred-percent-height-scrolling\"  style='background-color: #ffffff;background-position: left top;background-repeat: no-repeat;padding-right:0px;padding-bottom:0px;padding-left:0px;border-top-width:0px;border-bottom-width:0px;border-color:#e8eaf0;border-top-style:solid;border-bottom-style:solid;'><div class=\"fusion-builder-row fusion-row \"><div  class=\"fusion-layout-column fusion_builder_column fusion_builder_column_1_1 fusion-builder-column-3 fusion-one-full fusion-column-first fusion-column-last 1_1\"  style='margin-top:50px;margin-bottom:25px;'>\n\t\t\t\t\t<div class=\"fusion-column-wrapper\" style=\"padding: 0px 0px 0px 0px;background-position:left top;background-repeat:no-repeat;-webkit-background-size:cover;-moz-background-size:cover;-o-background-size:cover;background-size:cover;\"   data-bg-url=\"\">\n\t\t\t\t\t\t<div class=\"fusion-tabs fusion-tabs-1 clean vertical-tabs icon-position-left\"><style type=\"text\/css\">#wrapper .fusion-tabs.fusion-tabs-1.clean .nav-tabs li a{border-color:rgba(245,245,245,0);}.fusion-tabs.fusion-tabs-1 .nav-tabs li a{background-color:#f7f8f9;}.fusion-tabs.fusion-tabs-1 .nav-tabs li.active a,.fusion-tabs.fusion-tabs-1 .nav-tabs li.active a:hover,.fusion-tabs.fusion-tabs-1 .nav-tabs li.active a:focus{background-color:#a8cf45;}.fusion-tabs.fusion-tabs-1 .nav-tabs li a:hover{background-color:#a8cf45;border-top-color:#a8cf45;}.fusion-tabs.fusion-tabs-1 .tab-pane{background-color:#a8cf45;}.fusion-tabs.fusion-tabs-1 .nav,.fusion-tabs.fusion-tabs-1 .nav-tabs,.fusion-tabs.fusion-tabs-1 .tab-content .tab-pane{border-color:rgba(245,245,245,0);}<\/style><div class=\"nav\"><ul class=\"nav-tabs\"><li class=\"active\"><a class=\"tab-link\" data-toggle=\"tab\" id=\"fusion-tab-cellulosethickeners\" href=\"#tab-74154dd4a426fc1c67e\"><h4 class=\"fusion-tab-heading\">Cellulose thickeners<\/h4><\/a><\/li><li><a class=\"tab-link\" data-toggle=\"tab\" id=\"fusion-tab-acrylatethickeners\" href=\"#tab-979438d01c68462ac20\"><h4 class=\"fusion-tab-heading\">Acrylate thickeners<\/h4><\/a><\/li><li><a class=\"tab-link\" data-toggle=\"tab\" id=\"fusion-tab-polyurethanethickeners\" href=\"#tab-0a18d2c3d487ef389fa\"><h4 class=\"fusion-tab-heading\">Polyurethane thickeners<\/h4><\/a><\/li><\/ul><\/div><div class=\"tab-content\"><div class=\"nav fusion-mobile-tab-nav\"><ul class=\"nav-tabs\"><li class=\"active\"><a class=\"tab-link\" data-toggle=\"tab\" id=\"mobile-fusion-tab-cellulosethickeners\" href=\"#tab-74154dd4a426fc1c67e\"><h4 class=\"fusion-tab-heading\">Cellulose thickeners<\/h4><\/a><\/li><\/ul><\/div><div class=\"tab-pane fade fusion-clearfix in active\" id=\"tab-74154dd4a426fc1c67e\">\n<h2 style=\"font-weight: 300; margin-top: -20px; text-align: justify;\">Cellulose thickeners<\/h2>\n<p style=\"text-align: justify;\">Cellulose thickeners are chemical compounds derived from Cellulose ether families that are able to absorb water highly. In addition to increasing viscosity, they offer different properties e.g. stability, water retention, open-time, color development, etc.<\/p>\n<p style=\"text-align: justify;\">The pros of these thickeners are compatibility with different formulations and also different range of pH, but one of the cons of them is poor levelling effect. Further, these thickeners are not resistant to microorganism\u2019s attack. Hence, suggested to use in \u2013 can preservatives to prevent contamination.<\/p>\n<p style=\"text-align: justify;\">Types of cellulose thickeners:<\/p>\n<ul style=\"text-align: justify;\">\n<li>Hydroxyethyl cellulose (HEC)<\/li>\n<li>Methyl Hydroxy ethyl cellulose (MHEC)<\/li>\n<li>Hydroxy propyl methyl cellulose (HPMC)<\/li>\n<li>Ethyl Hydroxy ethyl cellulose (EHEC)<\/li>\n<li>Carboxymethyl Cellulose (CMC)<\/li>\n<\/ul>\n<p style=\"text-align: justify;\"><strong>Hydroxyethyl cellulose (HEC)<\/strong>: This thickener is applied for various industries including paints and coatings, adhesives, resins, cosmetics, detergents, etc. In paint and resin industry, Hydroxyethyl cellulose offers better feature comparing other Cellulose ether derivatives. The characteristics are as follows:<\/p>\n<ul style=\"text-align: justify;\">\n<li>Minimum effect on resin and paint gloss<\/li>\n<li>Pigment compatibility<\/li>\n<li>Better water retention<\/li>\n<li>Spatter resistance<\/li>\n<\/ul>\n<\/div><div class=\"nav fusion-mobile-tab-nav\"><ul class=\"nav-tabs\"><li><a class=\"tab-link\" data-toggle=\"tab\" id=\"mobile-fusion-tab-acrylatethickeners\" href=\"#tab-979438d01c68462ac20\"><h4 class=\"fusion-tab-heading\">Acrylate thickeners<\/h4><\/a><\/li><\/ul><\/div><div class=\"tab-pane fade fusion-clearfix\" id=\"tab-979438d01c68462ac20\">\n<h2 style=\"text-align: justify;\">Acrylate thickeners<\/h2>\n<p style=\"text-align: justify;\">Polyacrylate thickeners are acrylic copolymer emulsions. they are based on ASE (Alkali Swellable emulsions) and HASE (Hydrophobically Modified Alkali Swellable emulsions). these rheology modifiers can increase viscosity. Thanks to their liquid delivery form it is easy to incorporate. furthermore, due to their chemical structure they will not face microorganism attacks. By increasing pH to alkali range, they would absorb water and swell, and this process causes thickening effect.<\/p>\n<p style=\"text-align: justify;\">Difference between ASE and Associative acrylate thickeners (HASE) -which are also known as Hydrophobically Modified Alkali Swellable Emulsions, is that HASE contain hydrophobic groups that result more thickening efficiency, and improve scrub resistance.<\/p>\n<\/div><div class=\"nav fusion-mobile-tab-nav\"><ul class=\"nav-tabs\"><li><a class=\"tab-link\" data-toggle=\"tab\" id=\"mobile-fusion-tab-polyurethanethickeners\" href=\"#tab-0a18d2c3d487ef389fa\"><h4 class=\"fusion-tab-heading\">Polyurethane thickeners<\/h4><\/a><\/li><\/ul><\/div><div class=\"tab-pane fade fusion-clearfix\" id=\"tab-0a18d2c3d487ef389fa\">\n<h2 style=\"text-align: justify;\">Polyurethane thickeners (HEUR)<\/h2>\n<p style=\"text-align: justify;\">Polyurethane thickeners or Hydrophobically modified Ethylene oxide \u2013 based Urethane, are one of the innovative products among water \u2013 based thickeners. They can offer various features and provide good characteristic such as, levelling, scrub resistance, etc. moreover they perform in different range of pH and also will not face microorganism attack.<\/p>\n<\/div><\/div><\/div><div class=\"fusion-sep-clear\"><\/div><div class=\"fusion-separator fusion-full-width-sep sep-none\" style=\"margin-left: auto;margin-right: auto;margin-top:15px;\"><\/div><div class=\"fusion-title title fusion-title-2 fusion-sep-none fusion-title-size-two\" style=\"margin-top:10px;margin-bottom:20px;\"><h2 class=\"title-heading-left\" style=\"margin:0;\"><h3 style=\"padding-bottom: 5px;\">Fumed Silica<\/h3><\/h2><\/div><div class=\"fusion-sep-clear\"><\/div><div class=\"fusion-separator fusion-full-width-sep sep-none\" style=\"margin-left: auto;margin-right: auto;margin-top:15px;\"><\/div><div class=\"fusion-text\"><p style=\"text-align: justify;\">Fumed silica (CAS number 112945-52-5), also known as pyrogenic silica because it is produced in a flame, consists of microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles. The resulting powder has an extremely low bulk density and high surface area. Its three-dimensional structure results in viscosity-increasing, thixotropic behavior when used as a thickener or reinforcing filler.<\/p>\n<p style=\"text-align: justify;\">These products can be applied in:<\/p>\n<ul>\n<li>Coatings<\/li>\n<li>Printing Inks<\/li>\n<li>Adhesives<\/li>\n<li>Cosmetics<\/li>\n<li>Silicone elastomers (Like RTV, HTV)<\/li>\n<li>Food and Pharmaceutical products<\/li>\n<\/ul>\n<p style=\"text-align: justify;\">Generally fumed silica is divided to two main groups, including hydrophobic and hydrophilic.<\/p>\n<p style=\"text-align: justify;\">The other factor that can divide fumed silica to different grades is specific surface area and common grades are 150 m2\/g, 200 m2\/g, etc. The bigger surface area is, the more viscosity they give.<\/p>\n<\/div><div class=\"fusion-clearfix\"><\/div>\n\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><div class=\"fusion-fullwidth fullwidth-box nonhundred-percent-fullwidth non-hundred-percent-height-scrolling\"  style='background-color: rgba(255,255,255,0);background-position: center center;background-repeat: no-repeat;padding-right:0px;padding-bottom:0px;padding-left:0px;'><div class=\"fusion-builder-row fusion-row \"><div  class=\"fusion-layout-column fusion_builder_column fusion_builder_column_1_1 fusion-builder-column-4 fusion-one-full fusion-column-first fusion-column-last 1_1\"  style='margin-top:0px;margin-bottom:0px;'>\n\t\t\t\t\t<div class=\"fusion-column-wrapper\" style=\"padding: 0px 0px 0px 0px;background-position:left top;background-repeat:no-repeat;-webkit-background-size:cover;-moz-background-size:cover;-o-background-size:cover;background-size:cover;\"   data-bg-url=\"\">\n\t\t\t\t\t\t<div class=\"fusion-button-wrapper fusion-aligncenter\"><style type=\"text\/css\" scoped=\"scoped\">.fusion-button.button-1 .fusion-button-text, .fusion-button.button-1 i {color:#ffffff;}.fusion-button.button-1 {border-width:0px;border-color:#ffffff;}.fusion-button.button-1 .fusion-button-icon-divider{border-color:#ffffff;}.fusion-button.button-1:hover .fusion-button-text, .fusion-button.button-1:hover i,.fusion-button.button-1:focus .fusion-button-text, .fusion-button.button-1:focus i,.fusion-button.button-1:active .fusion-button-text, .fusion-button.button-1:active{color:#ffffff;}.fusion-button.button-1:hover, .fusion-button.button-1:focus, .fusion-button.button-1:active{border-width:0px;border-color:#ffffff;}.fusion-button.button-1:hover .fusion-button-icon-divider, .fusion-button.button-1:hover .fusion-button-icon-divider, .fusion-button.button-1:active .fusion-button-icon-divider{border-color:#ffffff;}.fusion-button.button-1{background: #a8cf45;}.fusion-button.button-1:hover,.button-1:focus,.fusion-button.button-1:active{background: #a8cf45;}.fusion-button.button-1{width:auto;}<\/style><a class=\"fusion-button button-flat fusion-button-square button-xlarge button-custom button-1\" target=\"_self\" href=\"http:\/\/kalakavan.com\/en\/contact-us\/\"><span class=\"fusion-button-text fusion-button-text-right\">more information<\/span><span class=\"fusion-button-icon-divider button-icon-divider-right\"><i class=\"fa-phone fas\"><\/i><\/span><\/a><\/div><div class=\"fusion-sep-clear\"><\/div><div class=\"fusion-separator fusion-full-width-sep sep-none\" style=\"margin-left: auto;margin-right: auto;margin-top:;margin-bottom:25px;\"><\/div><div class=\"fusion-clearfix\"><\/div>\n\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><\/p>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v20.13 - 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